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Two potential pyridine-borane oligomer and polymer building blocks. Structural characterisation of [NC5H4 center dot C5H4N center dot B10H12 center dot NC5H4 center dot C5H4N] and [Me2S center dot B10H12 center dot NC4H4N center dot B10H12 center dot SMe2] by conventional and synchrotron X-ray methods

Lookup NU author(s): Clayton Price, Emeritus Professor Bill CleggORCiD

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Abstract

Two five-unit Linear compounds, [NC5H4. C5H4N . B10H12. NC5H4. C5H4N] and [Me2S . B10H12. NC4H4N . B10H12. SMe2], have been isolated from the reactions of [6,9-(SMe2)(2)-arachno-B10H12] with 4,4'-bipyridyl and pyrazine (1,4-diazabenzene), respectively, and are characterised by single-crystal X-ray diffraction analysis. (C) 1999 Elsevier Science S.A. All rights reserved.

Publication metadata

Author(s): Londesborough MGS, Price C, Thornton-Pett M, Clegg W, Kennedy JD

Publication type: Article

Publication status: Published

Journal: Inorganic Chemistry Communications

Year: 1999

Volume: 2

Issue: 7

Pages: 298-300

Print publication date: 17/08/1999

ISSN (print): 1387-7003

ISSN (electronic): 1879-0259

Publisher: Elsevier BV

URL: http://dx.doi.org/10.1016/S1387-7003(99)00074-X

DOI: 10.1016/S1387-7003(99)00074-X

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