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Diaquabis(4-nitrobenzoato)zinc(II): a redetermination

Lookup NU author(s): Emeritus Professor Bill Clegg

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Abstract

The title compound, [Zn(O2CC6H4NO2)(2) (H2O)(2)], has zinc in a coordination geometry intermediate between tetrahedral and octahedral, with each carboxylate ligand forming a primary and a secondary Zn-O bond; the lengths of these differ by more than 0.5 Angstrom. The molecule has crystallographic twofold rotation symmetry. Intermolecular hydrogen bonds are formed between the aqua ligands as donors and carboxylate O atoms as acceptors, linking the molecules together into sheets, the closest contacts between which involve the nitro groups.


Publication metadata

Author(s): Necefoglu H, Clegg W, Scott AJ

Publication type: Article

Publication status: Published

Journal: Acta Crystallographica Section E: Structure Reports Online

Year: 2001

Volume: 57

Issue: 10

Pages: m472-m474

ISSN (print):

ISSN (electronic): 1600-5368

Publisher: Wiley-Blackwell Publishing, Inc.

URL: http://dx.doi.org/10.1107/S1600536801015082

DOI: 10.1107/S1600536801015082


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