Toggle Main Menu Toggle Search

Open Access padlockePrints

The Newcastle University research output collection, currently available on ePrints, will shortly be moving to a new open repository platform, Figshare. To prepare for the data migration we have paused adding new content to ePrints, and will resume once the new repository is launched. During this time you will continue to have access to ePrints (but no new content will appear). We will share updates here when available.

Self-assembly of a spin-coupled octanuclear copper(II) circular array from a single-stranded ligand

Lookup NU author(s): Dr Ross Harrington, Professor William Clegg

Downloads

Full text for this publication is not currently held within this repository. Alternative links are provided below where available.

Abstract

I was prepd. and reacted with CuX2 (X = ClO4, BF4, triflate) to give [Cu8L4(H2O)8]X16 (II). The bowed arrangement of bridging bidentate binding sites on I precludes a linear arrangement of metal ions. This conformation allows a spin-coupled octanuclear Cu(II) circular array of II to be formed from a single-stranded ligand. This circular array displays weak ferromagnetic exchange between metal centers and is a rare example of such an array contg. more than six centers. [on SciFinder (R)]

Publication metadata

Author(s): Onions ST, Heath SL, Price DJ, Harrington RW, Clegg W, Matthews CJ

Publication type: Article

Publication status: Published

Journal: Angewandte Chemie, International Edition

Year: 2004

Volume: 43

Issue: 14

Pages: 1814-1817

ISSN (print): 1433-7851

ISSN (electronic): 1521-3773

Publisher: Wiley - VCH Verlag GmbH & Co. KGaA

URL: http://dx.doi.org/10.1002/anie.200352554

DOI: 10.1002/anie.200352554

Notes: CAN 141:32882 78-7 Inorganic Chemicals and Reactions Chemistry Division, School of Science,Nottingham Trent University,Nottingham,UK. Journal 1433-7851 written in English. 697741-14-3P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and complexation with copper); 697745-97-4P Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (prepn. and ferromagnetic exchange and crystal structure of); 697741-13-2P; 697745-98-5P Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (prepn. and ferromagnetic exchange of); 1005-02-3; 697741-15-4 Role: RCT (Reactant), RACT (Reactant or reagent) (reactant for prepn. of bis(pyridinylamidinyl)pyrimidinediamidine)

Altmetrics

Altmetrics provided by Altmetric

Share