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Lookup NU author(s): Dr Ross Harrington,
Emeritus Professor Bill Clegg
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I was prepd. and reacted with CuX2 (X = ClO4, BF4, triflate) to give [Cu8L4(H2O)8]X16 (II). The bowed arrangement of bridging bidentate binding sites on I precludes a linear arrangement of metal ions. This conformation allows a spin-coupled octanuclear Cu(II) circular array of II to be formed from a single-stranded ligand. This circular array displays weak ferromagnetic exchange between metal centers and is a rare example of such an array contg. more than six centers. [on SciFinder (R)]
Author(s): Onions ST, Heath SL, Price DJ, Harrington RW, Clegg W, Matthews CJ
Publication type: Article
Publication status: Published
Journal: Angewandte Chemie, International Edition
ISSN (print): 1433-7851
ISSN (electronic): 1521-3773
Publisher: Wiley - VCH Verlag GmbH & Co. KGaA
Notes: CAN 141:32882
Inorganic Chemicals and Reactions
Chemistry Division, School of Science,Nottingham Trent University,Nottingham,UK.
written in English.
697741-14-3P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (prepn. and complexation with copper); 697745-97-4P Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (prepn. and ferromagnetic exchange and crystal structure of); 697741-13-2P; 697745-98-5P Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (prepn. and ferromagnetic exchange of); 1005-02-3; 697741-15-4 Role: RCT (Reactant), RACT (Reactant or reagent) (reactant for prepn. of bis(pyridinylamidinyl)pyrimidinediamidine)
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