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Dichlorobis(1,3-dimethylthiourea-kS)zinc(II)

Lookup NU author(s): Dr Ross Harrington

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Abstract

Crystals of the title compd. are monoclinic, space group C2/c, with a 13.0230(4), b 8.9470(3), c 12.4350(3).ANG., beta 106.967(2) Deg; Z = 4, dc = 1.652; R = 0.028, Rw(F2) = 0.067 for 1580 reflections. There is a distorted tetrahedral geometry around the Zn center which occupies a 2-fold axis. Both intra- and intermol. H bonding is obsd. between the 1,3-dimethylthiourea NH groups and the coordinated Cl atoms. [on SciFinder (R)]


Publication metadata

Author(s): Burrows AD, Harrington RW, Mahon MF

Publication type: Article

Publication status: Published

Journal: Acta Crystallographica, Section E: Structure Reports Online

Year: 2004

Volume: E60

Issue: 9

Pages: m1317-m1318

ISSN (electronic): 1600-5368

Publisher: Wiley-Blackwell Publishing, Inc.

URL: http://dx.doi.org/10.1107/S1600536804020550

DOI: 10.1107/S1600536804020550

Notes: CAN 142:46217 75-8 Crystallography and Liquid Crystals Department of Chemistry,University of Bath,Claverton Down, Bath,UK. Journal; Online Computer File 1600-5368 written in English. 17993-11-2 (Dichlorobis(1,3-dimethylthiourea-kS)zinc(II) Role: PRP (Properties) (crystal structure of)


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