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Enhancement of H₂ adsorption in Li⁺-exchanged co-ordination framework materials

Lookup NU author(s): Emeritus Professor Mark ThomasORCiD

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Abstract

H-2 adsorption in (Me2NH2)[In(L)] is enhanced by exchange of Me2NH2+ for Li+ cations; the Li+-exchanged material displays a lower isosteric heat for H-2 adsorption than the parent material, indicating that the increase in H-2 capacity is due to an increase in the accessible pore volume on cation exchange, while the lower adsorption enthalpy is consistent with increased pore size.

Publication metadata

Author(s): Yang S, Lin X, Blake AJ, Thomas KM, Hubberstey P, Champness NR, Schroder M

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 2008

Issue: 46

Pages: 6108-6110

Print publication date: 01/01/2008

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b814155j

DOI: 10.1039/b814155j

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