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Lookup NU author(s): Diana Suarez,
Dr Gilles Laval,
Dr Richard Scott,
Professor Bernard Golding
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A variety of benzylic brominations were performed by Using N-bromosuccinimide in (trifluoromethyl)benzene with photochemical activation in the presence of 2.2'-azobisisobutyronitrile, 1,1'-azobis(cyclohexanecarbonitrile), or benzoyl peroxide as the radical initiator. This system provides clean, rapid, and high-yielding reactions with replacement of conventional solvents, such as tetrachloromethane, by less-toxic (trifluoromethyl)benzene.
Author(s): Suarez D, Laval G, Tu SM, Jiang D, Robinson CL, Scott R, Golding BT
Publication type: Article
Publication status: Published
ISSN (print): 0039-7881
ISSN (electronic): 1437-210X
Publisher: Georg Thieme Verlag
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