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Bis(tetraphenylphosphonium) (hexasulfido-2 kappa S-2(1),S-6)di-mu-sulfido-disulfido-1 kappa S-2-tungsten(VI)zinc(II) acetone solvate

Lookup NU author(s): Emeritus Professor Bill CleggORCiD, Dr Sophie Dale

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Abstract

The title complex, (C24H20P)(2)[WZnS4(S-6)]center dot C3H6O or (Ph4P)(2)-[WS2(mu-S)(2){Zn(S-6)}] center dot Me2CO, was unexpectedly obtained on attempted recrystallization of a mixed tungten-zinc complex of a tris(pyrazolato) borate ligand. The two metal centres of the anion have distorted tetrahedral coordination and the two tetrahedra share one S center dot center dot center dot S edge; tungsten is additionally coordinated by two terminal sulfide ligands and zinc by a chelating S-6(2-) ligand, which has one central S-S bond significantly longer than the other four, a pattern found to be consistent for this ligand. This is the first reported example of a tetrahedral zinc centre bridging an edge of a single tetrathiotungstate( VI) or tetrathiomolybdate(VI) anion, although there are many previous examples with other metals.

Publication metadata

Author(s): Beheshti A, Clegg W, Dale SH, Hyvadi R

Publication type: Article

Publication status: Published

Journal: Acta Crystallographica. Section C: Crystal Structure Communications

Year: 2009

Volume: 65

Issue: 9

Pages: M331-M332

ISSN (print): 0108-2701

ISSN (electronic): 1600-5759

Publisher: Wiley-Blackwell Munksgaard

URL: http://dx.doi.org/10.1107/S0108270109029072

DOI: 10.1107/S0108270109029072

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