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(Acetato-kappa O)[tris(3,5-dimethylpyrazol-1-yl-kappa N-2)hydroborato]zinc(II)

Lookup NU author(s): Emeritus Professor Bill Clegg, Dr Sophie Dale

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Abstract

The title complex, [Zn(C15H22BN6)(C2H3O2)] or (Tp(Me,Me))Zn(OAc), contains a tripodal tris(pyrazolyl)hydroborate ligand, a monodentate acetate ligand and a Zn-II centre in a distorted tetrahedral coordination environment capped on one triangular face by a secondary Zn center dot center dot center dot O interaction with the second O atom of the acetate ligand. The four-coordination of Zn-II and the essentially monodentate character of the acetate ligand are due to the high steric demands of the ligand set, which prevent chelate formation and five-coordination and lead to relatively long Zn-O and Zn-N bonds compared with related complexes of Zn-II and other metals.


Publication metadata

Author(s): Beheshti A, Clegg W, Dale SH, Hyvadi R

Publication type: Article

Publication status: Published

Journal: Acta Crystallographica. Section C: Crystal Structure Communications

Year: 2009

Volume: 65

Issue: 8

Pages: M314-M316

ISSN (print): 0108-2701

ISSN (electronic): 1600-5759

Publisher: Wiley-Blackwell Munksgaard

URL: http://dx.doi.org/10.1107/S0108270109027516

DOI: 10.1107/S0108270109027516


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