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Gold(I) Complexes of KITPHOS Monophosphines: Efficient Cycloisomerisation Catalysts

Lookup NU author(s): Dr Julian Knight, Dr Simon DohertyORCiD


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Gold (I)-triflimide (AuNTf2)complexes of H-KITPHOS and o-MeO-KITPHOS have been prepared and shown to be efficient catalysts for a range of intramolecular cyclisations to afford phenols, acylindenes, alkylidene oxazoles, tetrahydropyrans and lactones, in the majority of cases these catalysts are superior to those previously reported.

Publication metadata

Author(s): Hashmi ASK, Loos A, Littmann A, Braun I, Knight J, Doherty S, Rominger F

Publication type: Article

Publication status: Published

Journal: Advanced Synthesis & Catalysis

Year: 2009

Volume: 351

Issue: 4

Pages: 576-582

ISSN (print): 1615-4150

ISSN (electronic): 1615-4169

Publisher: Wiley - V C H Verlag GmbH & Co. KGaA


DOI: 10.1002/adsc.200800681


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Funder referenceFunder name
Umicore AG Co.
1932/10-1Deutsche Forschungsgemeinschaft