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Lookup NU author(s): Dr Simon Doherty,
Dr Ross Harrington,
Emeritus Professor Bill Clegg
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Cationic rhodium complexes based on (R)-BINAP catalyze the sequential double [2 + 2 + 2] cycloaddition between 1,4-bis(diphenylphosphinoyl)buta-1,3-diyne and an internal 2,n-diyne followed by its terminal counterpart in an operationally straightforward procedure to afford pseudo-C-2-symmetric axially chiral biaryl diphosphines in good yield and with exceptionally high enantioselectivity.
Author(s): Doherty S, Smyth CH, Harrington RW, Clegg W
Publication type: Article
Publication status: Published
ISSN (print): 0276-7333
ISSN (electronic): 1520-6041
Publisher: American Chemical Society
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