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Mononuclear Ti N complexes formed by the facile multiple deprotonation of H3N center dot B(C6F5)(3): the importance of chloride ligands

Lookup NU author(s): Emeritus Professor Bill CleggORCiD, Dr Ross Harrington


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The crystalline ion-pair [TiCl(NMe2)(2)(NMe2H)(2)](+)[TiCl2{NB- (C6F5)(3)}(NMe2H)(2)](-), in which the anion has a triply bonded nitridoborate ligand, is formed through the multiple activation of H3N center dot B(C6F5)(3) when treated with [Ti(NMe2)(3)Cl].

Publication metadata

Author(s): Fuller AM, Clegg W, Harrington RW, Hughes DL, Lancaster SJ

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 2008

Issue: 44

Pages: 5776-5778

Print publication date: 01/01/2008

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: Royal Society of Chemistry


DOI: 10.1039/b812785a


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