Toggle Main Menu Toggle Search

Open Access padlockePrints

Synthesis and crystal structure of bis[N-(phenyl)-3,5-dinitrothiobenzamidato]mercury(II) and bis[N-(phenyl)-4-nitrothiobenzamidato]mercury(II)

Lookup NU author(s): Professor Mohammad Habibi, Emeritus Professor Bill Clegg

Downloads

Full text for this publication is not currently held within this repository. Alternative links are provided below where available.


Abstract

The crystal structures of bis[N-(phenyl)-3,5-dinitrothiobenzamidato]mercury(II) (1) and bis[N-(phenyl)-4-nitrothiobenzamidato]mercury(II) (2) have been determined by single-crystal X-ray diffraction. Compound 1 is in the monoclinic space group P2(1)/n with a = 11.770(2), b = 7.0589(12), c = 17.031(2) angstrom, beta = 110.216(10)degrees, V = 1327.8(4) angstrom(3) and Z = 2. Compound 2 is in the monoclinic space group P2(1)/c with a = 9.5232(3), b = 6.6685(6), c = 19.3902(14) angstrom, beta = 99.412(5)degrees, V = 1214.81(15) angstrom(3) and Z = 2. The S-Hg-S is linear with angle of 180 degrees. In the crystal packing, the molecules are linked via weak intra-and intermolecular C-H center dot center dot center dot O, N, and S hydrogen bonds.


Publication metadata

Author(s): Habibi MH, Fallah-Shojaiea A, Barati K, Clegg W

Publication type: Article

Publication status: Published

Journal: Journal of Coordination Chemistry

Year: 2009

Volume: 62

Issue: 22

Pages: 3712-3718

Print publication date: 01/01/2009

ISSN (print): 0095-8972

ISSN (electronic): 1029-0389

Publisher: Taylor & Francis Ltd.

URL: http://dx.doi.org/10.1080/00958970802695805

DOI: 10.1080/00958970802695805


Altmetrics

Altmetrics provided by Altmetric


Actions

Find at Newcastle University icon    Link to this publication


Share