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Lookup NU author(s): Professor Mohammad Habibi,
Emeritus Professor Bill CleggORCiD
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The crystal structures of bis[N-(phenyl)-3,5-dinitrothiobenzamidato]mercury(II) (1) and bis[N-(phenyl)-4-nitrothiobenzamidato]mercury(II) (2) have been determined by single-crystal X-ray diffraction. Compound 1 is in the monoclinic space group P2(1)/n with a = 11.770(2), b = 7.0589(12), c = 17.031(2) angstrom, beta = 110.216(10)degrees, V = 1327.8(4) angstrom(3) and Z = 2. Compound 2 is in the monoclinic space group P2(1)/c with a = 9.5232(3), b = 6.6685(6), c = 19.3902(14) angstrom, beta = 99.412(5)degrees, V = 1214.81(15) angstrom(3) and Z = 2. The S-Hg-S is linear with angle of 180 degrees. In the crystal packing, the molecules are linked via weak intra-and intermolecular C-H center dot center dot center dot O, N, and S hydrogen bonds.
Author(s): Habibi MH, Fallah-Shojaiea A, Barati K, Clegg W
Publication type: Article
Publication status: Published
Journal: Journal of Coordination Chemistry
Print publication date: 01/01/2009
ISSN (print): 0095-8972
ISSN (electronic): 1029-0389
Publisher: Taylor & Francis Ltd.
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