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Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations

Lookup NU author(s): Emeritus Professor Bill CleggORCiD, Dr Luca Russo

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Abstract

Direct zincation of ferrocene and ruthenocene by the synergic base [PMDETA center dot K(mu-TMP)(mu-Me)Zn(Me)] produces the monozincated complexes [{PMDETA center dot K(mu-Me)(2)Zn(Fc)}(infinity)] and [{PMDETA center dot K(mu-Me)(2)Zn(Rc)}(2)], respectively, having similar monomeric (dinuclear) units but aggregating supramolecularly in very different polymeric and dimeric forms.

Publication metadata

Author(s): Clegg W, Conway B, Garcia-Alvarez P, Kennedy AR, Klett J, Mulvey RE, Russo L

Publication type: Article

Publication status: Published

Journal: Dalton Transactions

Year: 2010

Volume: 39

Issue: 1

Pages: 62-65

Print publication date: 01/01/2010

ISSN (print): 1477-9234

ISSN (electronic): 1477-9226

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b917202p

DOI: 10.1039/b917202p

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