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Lookup NU author(s): Professor Michael North,
Dr Pedro Villuendas
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The combination of a bimetallic aluminium(salen) complex and tetrabutylammonium bromide was found to catalyse the synthesis of cyclic di- and trithiocarbonates from epoxides and carbon disulfide. Reactions carried out at 50 degrees C produced 1,3-oxathiolane-2-thiones, whilst at 90 degrees C, 1,3-dithiolane-2-thiones were formed.
Author(s): North M, Villuendas P
Publication type: Article
Publication status: Published
Print publication date: 01/03/2010
ISSN (print): 0936-5214
ISSN (electronic): 1437-2096
Publisher: Georg Thieme Verlag
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