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Expanded-Ring and Backbone-Functionalised N-Heterocyclic Carbenes

Lookup NU author(s): Dr Ross Harrington, Professor William Clegg

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Abstract

An unsaturated seven-membered amidinium salt 7 decomposes in the presence of metal salts under basic conditions. However, 7 readily forms a Diels-Alder cycloadduct with CpH from which the Rh-I complexes may be prepared. Thus, structurally elaborate, sterically crowded carbene ligand complexes bearing peripheral unsaturated functionality are available in a short versatile synthesis.

Publication metadata

Author(s): Iglesias M, Beetstra DJ, Cavell KJ, Deryisi A, Fallis IA, Kariuki B, Harrington RW, Clegg W, Horton PN, Coles SJ, Hursthouse MB

Publication type: Article

Publication status: Published

Journal: European Journal of Inorganic Chemistry

Year: 2010

Issue: 11

Pages: 1604-1607

Print publication date: 11/03/2010

ISSN (print): 1434-1948

ISSN (electronic): 1099-0682

Publisher: Wiley - VCH Verlag GmbH & Co. KGaA

URL: .http:/dx.doi.org/10.1002/ejic.200901182

DOI: 10.1002/ejic.200901182

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Funding

Funder referenceFunder name
Science and Technology Facilities Council (STFC)
National Crystallography Service
EP/C528638/1Engineering and Physical Sciences Research Council (EPSRC)
EP/C53090X/1Engineering and Physical Sciences Research Council (EPSRC)
GR/R06458/01Engineering and Physical Sciences Research Council (EPSRC)
GR/S86105/01Engineering and Physical Sciences Research Council (EPSRC)

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