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Bis-TADDOLs as bifunctional organocatalysts for trifluoromethylation of aldehydes and ring-opening of cyclohexene oxide with p-toluidine

Lookup NU author(s): Professor Michael North

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Abstract

A set of bis-TADDOLs, in which two TADDOL moieties are connected by different linkers, have been prepared. A great dependence of the catalytic activities of the bis-TADDOLs on the distance between the TADDOL moieties was found by the addition of trifluoromethyltrimethylsilane to benzaldehyde and ring-opening of cyclohexene oxide with or without alkali metal salts added. (C) 2010 Elsevier Ltd. All rights reserved.

Publication metadata

Author(s): Belokon YN, Gugkaeva ZT, Maleev VI, Moskalenko MA, North M, Tsaloev AT

Publication type: Article

Publication status: Published

Journal: Tetrahedron: Asymmetry

Year: 2010

Volume: 21

Issue: 13-14

Pages: 1793-1796

Print publication date: 01/07/2010

ISSN (print): 0957-4166

ISSN (electronic): 1362-511X

Publisher: Pergamon

URL: http://dx.doi.org/10.1016/j.tetasy.2010.05.030

DOI: 10.1016/j.tetasy.2010.05.030

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