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Lookup NU author(s): Professor Michael North
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In the presence of chiral catalysts derived from the same chiral hexadentate ligand and aluminium, zinc or titanium ions, the reaction between cyclohexene oxide and trimethylsilyl cyanide can be controlled to give predominantly either the nitrile (up to 99% ee) or the isonitrile product (up to 94% ee). The metal ion, ligand stereochemistry and base concentration all play a role in determining the product ratio. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Author(s): Belokon Y, Chusov D, Peregudov A, Yashkina L, Timofeeva G, Maleev V, North M, Kagan H
Publication type: Article
Publication status: Published
Journal: Advanced Synthesis and Catalysis
ISSN (print): 1615-4150
ISSN (electronic): 1615-4169
Publisher: Wiley - VCH Verlag GmbH & Co. KGaA
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