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Lookup NU author(s): Professor Mohammad Habibi,
Dr Neil Brooks,
Emeritus Professor Bill Clegg
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The crystal structures of bis(N-phenyl-3,5-dinitrothiobenzamidato)mercury(II) (1) and bis(N-phenyl-4-nitrothiobenzamidato)mercury(II) (2) have been determined by single-crystal X-ray diffraction. Both the complexes crystallize in centrosymmetric monoclinic space groups with crystallographic inversion symmetry. The S-Hg-S linkage is thus precisely linear in each case. Significant secondary interactions include intramolecular Φ coordination by phenyl groups, aromatic ring stacking in the case of 1 only, and a number of intramolecular and intermolecular C-H...X contacts (X=O, N, S) influencing the molecular conformation and crystal packing. © 2010 Taylor & Francis.
Author(s): Habibi M, Tangestaninejad S, Fallah-Shojaei A, Barati K, Brooks N, Clegg W
Publication type: Article
Publication status: Published
Journal: Journal of Coordination Chemistry
Print publication date: 01/02/2010
ISSN (print): 0095-8972
ISSN (electronic): 1026-7441
Publisher: Taylor & Francis Ltd.
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