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Yb3O(OH)(6)Cl center dot 2H(2)O: An Anion-Exchangeable Hydroxide with a Cationic Inorganic Framework Structure

Lookup NU author(s): Emeritus Professor Bill Clegg, Dr Ross Harrington

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Abstract

The first anion-exchangeable framework hydroxide, Yb3O(OH)(6)Cl center dot 2H(2)O, has been synthesized hydrothermally. This material has a three-dimensional cationic ytterbium oxyhydroxide framework with one-dimensional channels running through the structure in which the chloride anions and water molecules are located. The framework is thermally stable below 200 degrees C and can be reversibly dehydrated and rehydrated with no loss of crystallinity. Additionally, it is able to undergo anion-exchange reactions with small ions such as carbonate, oxalate, and succinate with retention of the framework structure.


Publication metadata

Author(s): Goulding HV, Hulse SE, Clegg W, Harrington RW, Playford HY, Walton RI, Fogg AM

Publication type: Article

Publication status: Published

Journal: Journal of the American Chemical Society

Year: 2010

Volume: 132

Issue: 39

Pages: 13618-13620

Print publication date: 08/07/2010

ISSN (print): 0002-7863

ISSN (electronic): 1520-5126

Publisher: American Chemical Society

URL: http://dx.doi.org/10.1021/ja104636x

DOI: 10.1021/ja104636x


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