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Lookup NU author(s): Emeritus Professor Bill Clegg,
Dr Ross Harrington
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The first anion-exchangeable framework hydroxide, Yb3O(OH)(6)Cl center dot 2H(2)O, has been synthesized hydrothermally. This material has a three-dimensional cationic ytterbium oxyhydroxide framework with one-dimensional channels running through the structure in which the chloride anions and water molecules are located. The framework is thermally stable below 200 degrees C and can be reversibly dehydrated and rehydrated with no loss of crystallinity. Additionally, it is able to undergo anion-exchange reactions with small ions such as carbonate, oxalate, and succinate with retention of the framework structure.
Author(s): Goulding HV, Hulse SE, Clegg W, Harrington RW, Playford HY, Walton RI, Fogg AM
Publication type: Article
Publication status: Published
Journal: Journal of the American Chemical Society
Print publication date: 08/07/2010
ISSN (print): 0002-7863
ISSN (electronic): 1520-5126
Publisher: American Chemical Society
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