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Lookup NU author(s): Arne Ficks,
Dr Ross Harrington,
Dr Lee HighamORCiD
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Chiral phosphonite ligands (S,Rb)-5a, (S,Sb)-5b, (R,Rb)-6a and (R,Sb)-6b are introduced, comprising a MOP-type backbone with a binol-based binaphthyl group bound to the phosphorus. Their reaction with [Pd(η3-C4H7)Cl]2 affords η3-methallylpalladium chloride complexes 7a/b and 8a/b which have been isolated and structurally characterised. Solid-state and solution studies indicate subtle differences in their coordination behaviour, which ultimately affects their efficacy in the asymmetric hydrosilylation of styrene.
Author(s): Ficks A, Hiney RM, Harrington RW, Gilheany DG, Higham LJ
Publication type: Article
Publication status: Published
Journal: Dalton Transactions
Print publication date: 03/02/2012
ISSN (print): 1477-9226
ISSN (electronic): 1477-9234
Publisher: Royal Society of Chemistry
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