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Lookup NU author(s): Arne Ficks,
Dr Ross Harrington,
Emeritus Professor Bill Clegg,
Dr Lee Higham
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Air-stable, chiral primary phosphines have been synthesized on a multigram scale. The key synthetic step is an optimized palladium-catalyzed phosphonylation reaction of aryltriflates, which opens up a valuable synthetic route to a chiral scaffold that is easily derivatized into novel phosphines.
Author(s): Ficks A, Sibbald C, Ojo S, Harrington RW, Clegg W, Higham LJ
Publication type: Article
Publication status: Published
Print publication date: 01/01/2013
ISSN (print): 0039-7881
ISSN (electronic): 1437-210X
Publisher: Georg Thieme Verlag
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