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Selective formation of a polar incomplete coordination cage induced by remote ligand substituents

Lookup NU author(s): Emeritus Professor Bill Clegg, Dr Ross Harrington

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Abstract

Instead of highly symmetrical T-symmetry cages common in self-assembly, the p-NMe2-substituted triphosphine CH3C{CH2P(4-C6H4NMe2)(3) gives open, polar C-3 symmetry cages [Ag-6(triphos)(4)X-3](3+) which lack one of the expected face-capping anions; despite its subtlety this difference occurs selectively in solution and two examples have been crystallographically characterised.


Publication metadata

Author(s): Giri N, Clegg W, Harrington RW, Horton PN, Hursthouse MB, James SL

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 2012

Volume: 48

Issue: 34

Pages: 4061-4063

Print publication date: 21/03/2012

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/c2cc17832j

DOI: 10.1039/c2cc17832j


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