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Chiral MOP-phosphonite ligands: synthesis, characterisation and interconversion of η¹,η⁶-(σ-P, π-arene) chelated rhodium(I) complexes

Lookup NU author(s): Arne Ficks, Dr Ross Harrington, Dr Lee HighamORCiD

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Abstract

The synthesis of rhodium(I) and iridium(I) complexes of chiral MOP-phosphonite ligands is reported. The full characterisation of η¹,η⁶-(σ-P, π-arene) chelated 18VE rhodium(I) complexes reveals hemilabile binding on the arene which has been quantitatively analysed.

Publication metadata

Author(s): Ficks A, Harrington RW, Higham LJ

Publication type: Article

Publication status: Published

Journal: Dalton Transactions

Year: 2013

Volume: 42

Issue: 18

Pages: 6302-6305

Print publication date: 14/05/2013

Online publication date: 25/03/2013

Acceptance date: 22/02/2013

Date deposited: 04/11/2014

ISSN (print): 1477-9226

ISSN (electronic): 1477-9234

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/c3dt50482d

DOI: 10.1039/c3dt50482d

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