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A redox-triggered structural rearrangement in an iodate-templated polyoxotungstate cluster cage

Lookup NU author(s): Dr John Errington

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Abstract

The new tungstatoiodate, α-[H5W18O59(IO3)]6−, containing IVO3− within a {W18O54} metal oxide framework has been prepared and shown by X-ray crystallography and mass spectrometry to be derived from the fully oxidised [H3W18O56(IO6)]6− by two-electron reduction accompanied by a redox-triggered structural rearrangement where three I–O covalent bonds are broken.


Publication metadata

Author(s): Long D-L, de la Oliva AR, Yan J, Busche C, Miras HN, Errington J, Cronin L

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 2013

Volume: 49

Issue: 84

Pages: 9731-9733

Print publication date: 02/09/2013

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/C3CC45659E

DOI: 10.1039/C3CC45659E


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