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Marked enantioselectivity enhancements for Diels-Alder reactions in ionic liquids catalysed by platinum diphosphine complexes

Lookup NU author(s): Dr Simon DohertyORCiD

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Abstract

Asym. Diels-Alder reactions using platinum complexes of BINAP, or of conformationally flexible NUPHOS-type diphosphines, have been compared in dichloromethane and selected ionic liqs. Significant enhancements in the enantioselectivity (delta ee delta 20%), as well as reaction rate, were achieved in ionic liqs. compared with the org. media.

Publication metadata

Author(s): Doherty S; Goodrich P; Hardacre C; Luo H-K; Rooney DW; Seddon KR; Styring P

Publication type: Article

Publication status: Published

Journal: Green Chemistry

Year: 2003

Volume: 6

Issue: 1

Pages: 63-67

ISSN (print): 1463-9262

ISSN (electronic): 1463-9270

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b312761c

DOI: 10.1039/b312761c

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