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Chiral Octahedral Complexes of CoIII As a Family of Asymmetric Catalysts Operating under Phase Transfer Conditions

Lookup NU author(s): Professor Michael North

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Abstract

Stereochemically inert and positively charged chiral complexes of Co-III prepared from Schiff bases derived from chiral diamines and salicylaldehydes were shown to be efficient catalysts of the asymmetric phase transfer benchmark reaction of alkylation of O'Donnell's substrate with alkyl halides. The enantiomeric purities of the reaction products were up to 92%.

Publication metadata

Author(s): Belokon YN, Maleev VI, North M, Larionov VA, Savel'yeva TF, Nijland A, Nelyubina YV

Publication type: Article

Publication status: Published

Journal: ACS Catalysis

Year: 2013

Volume: 3

Issue: 9

Pages: 1951-1955

Print publication date: 06/09/2013

Online publication date: 17/07/2013

Acceptance date: 09/07/2013

ISSN (electronic): 2155-5435

Publisher: American Chemical Society

URL: http://dx.doi.org/10.1021/cs400409d

DOI: 10.1021/cs400409d

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Funding

Funder referenceFunder name
13-03-92601-KO-aRFBR

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