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Lookup NU author(s): Professor William Clegg, Dr Luca Russo
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Using structurally well-defined dipotassium-tetra(alkyl)magnesiates, a new straightforward methodology to promote regioselective Mg-H exchange reactions of a wide range of aromatic and heteroaromatic substrates is disclosed. Contacted ion pair intermediates are likely to be involved, with K being the key to facilitate the magnesiation processes.
Author(s): Baillie SE, Bluemke TD, Clegg W, Kennedy AR, Klett J, Russo L, de Tullio M, Hevia E
Publication type: Article
Publication status: Published
Journal: Chemical Communications
Year: 2014
Volume: 50
Issue: 85
Pages: 12859-12862
Print publication date: 04/11/2014
Online publication date: 03/09/2014
Acceptance date: 02/09/2014
ISSN (print): 1359-7345
ISSN (electronic): 1364-548X
Publisher: RSC Publications
URL: http://dx.doi.org/10.1039/c4cc05305b
DOI: 10.1039/c4cc05305b
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