ePrints

A high-pressure crystallographic and magnetic study of Na-₅[Mn(L-tart)₂]^.12H₂O (_L-tart = _L-tartrate)

Lookup NU author(s): Professor Mike ProbertORCiD

Downloads

• Published version [.pdf]

Licence

This work is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0).

Abstract

The crystal structure and magnetic properties of the compound Na-5[Mn(L-tart)2]center dot 12H(2)O ( 1, L-tart = L-tartrate) have been investigated over the pressure range 0.34-3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na+ ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.

Publication metadata

Author(s): Craig GA, Woodall CH, McKellar SC, Probert MR, Kamenev KV, Moggach SA, Brechin EK, Parsons S, Murrie M

Publication type: Article

Publication status: Published

Journal: Dalton Transactions

Year: 2015

Volume: 44

Issue: 42

Pages: 18324-18328

Print publication date: 14/11/2015

Online publication date: 30/09/2015

Acceptance date: 29/09/2015

Date deposited: 20/04/2016

ISSN (print): 1477-9226

ISSN (electronic): 1477-9234

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/C5DT03320A

DOI: 10.1039/c5dt03320a

Altmetrics

Funding

Share