Browse by author
Lookup NU author(s): Professor Thomas Penfold
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License (CC BY-NC 4.0).
Ultrafast pump-probe spectroscopy within the X-ray regime is now possible owing to the development of X-ray Free Electrons Lasers (X-FELs) and is opening new opportunities for the direct probing of femtosecond evolution of the nuclei, the electronic and spin degrees of freedom. In this contribution we use wavepacket dynamics of the photoexcited decay of a new Fe(II) complex, [Fe(bmip)2]2+ (bmip=2,6-bis(3-methyl-imidazole-1-ylidine)pyridine), to simulate the experimental observables associated with femtosecond Fe K-edge X-ray Absorption Near-Edge Structure (XANES) and X-ray Emission (XES) spectroscopy. We show how the evolution of the nuclear wavepacket is translated into the spectroscopic signal and the sensitivity of these approaches for following excited state dynamics.
Author(s): Penfold T, Pápai M, Rozgonyi T, Møller K, Vankó G
Publication type: Article
Publication status: Published
Journal: Faraday Discussions
Year: 2016
Volume: 194
Pages: 731-746
Print publication date: 01/12/2016
Online publication date: 17/05/2016
Acceptance date: 17/05/2016
Date deposited: 17/05/2016
ISSN (print): 1359-6640
ISSN (electronic): 1364-5498
Publisher: Royal Society of Chemistry
URL: http://dx.doi.org/10.1039/C6FD00070C
DOI: 10.1039/C6FD00070C
Altmetrics provided by Altmetric