Browse by author
Lookup NU author(s): Dr Thomas PopeORCiD
Full text for this publication is not currently held within this repository. Alternative links are provided below where available.
We report an electrochemical gating approach with ~100% efficiency to tune the conductance of single-molecule 4,4′-bipyridine junctions using scanning-tunnelling-microscopy break junction technique. Density functional theory calculation suggests that electrochemical gating aligns molecular frontier orbitals relative to the electrode Fermi-level, switching the molecule from an off resonance state to "partial" resonance.
Author(s): Baghernejad M, Manrique DZ, Li C, Pope T, Zhumaev U, Pobelov I, Moreno-García P, Kaliginedi V, Huang C, Hong W, Lambert CJ, Wandlowski T
Publication type: Article
Publication status: Published
Journal: Chemical Communications
Year: 2014
Volume: 50
Issue: 100
Pages: 15975–15978
Print publication date: 04/11/2014
Online publication date: 04/11/2014
Acceptance date: 04/11/2014
ISSN (print): 1359-7345
ISSN (electronic): 1364-548X
Publisher: Royal Society of Chemistry
URL: http://dx.doi.org/10.1039/C4CC06519K
DOI: 10.1039/C4CC06519K
Altmetrics provided by Altmetric