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Microwave synthesis of noncentrosymmetric BaTiO3 truncated nanocubes for charge storage applications

Lookup NU author(s): Dr Stevin PramanaORCiD


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Truncated nanocubes of barium titanate (BT) were synthesized using a rapid, facile microwave-assisted hydrothermal route. Stoichiometric composition of pellets of nanocube BT powders was prepared by two-stage microwave process. Characterization by powder XRD, Rietveld refinement, SEM, TEM, and dielectric and polarization measurements was performed. X-ray diffraction revealed a polymorphic transformation from cubic Pm3̄m to tetragonal P4mm after 15 min of microwave irradiation, arising from titanium displacement along the c-axis. Secondary electron images were examined for nanocube BT synthesis and annealed at different timings. Transmission electron microscopy showed a narrow particle size distribution with an average size of 70 ± 9 nm. The remanence and saturation polarization were 15.5 ± 1.6 and 19.3 ± 1.2 μC/cm2, respectively. A charge storage density of 925 ± 47 nF/cm2 was obtained; Pt/BT/Pt multilayer ceramic capacitor stack had an average leakage current density of 5.78 ± 0.46 × 10-8 A/cm2 at ±2 V. The significance of this study shows an inexpensive and facile processing platform for synthesis of high-k dielectric for charge storage applications. © 2010 American Chemical Society.

Publication metadata

Author(s): Swaminathan V, Pramana SS, White TJ, Chen L, Chukka R, Ramanujan RV

Publication type: Article

Publication status: Published

Journal: ACS Applied Materials and Interfaces

Year: 2010

Volume: 2

Issue: 11

Pages: 3037-3042

Print publication date: 24/11/2010

Online publication date: 14/10/2010

ISSN (print): 1944-8244

ISSN (electronic): 1944-8252

Publisher: American Chemical Society


DOI: 10.1021/am1004865


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