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Lookup NU author(s): Rua Alnoman, Patrycja Stachelek, Dr Julian Knight, Emeritus Professor Anthony Harriman, Dr Paul Waddell
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License (CC BY-NC 4.0).
Palladium catalysed coupling of the 2-iodoBODIPY 3 with a range of anilines and a primary alkylamine succeeds in generating the corresponding 2-aminoBODIPYs. These 2-aminoBODIPY derivatives are non-emissive and quantum chemical calculations and electrochemistry are consistent with charge transfer from the amine substituent. Attenuation of this charge transfer pathway by conversion of the 1,2-phenylenediamine derivative 9 into the corresponding benzimidazolone 10 restores the fluorescence and has been used as the basis for a fluorescence sensor for phosgene.
Author(s): Alnoman RB, Stachelek P, Knight JG, Harriman A, Waddell PG
Publication type: Article
Publication status: Published
Journal: Organic and Biomolecular Chemistry
Year: 2017
Volume: 15
Issue: 36
Pages: 7643-7653
Print publication date: 28/09/2017
Online publication date: 31/08/2017
Acceptance date: 17/08/2017
Date deposited: 18/08/2017
ISSN (print): 1477-0520
ISSN (electronic): 1477-0539
Publisher: Royal Society of Chemistry
URL: https://doi.org/10.1039/C7OB01767G
DOI: 10.1039/C7OB01767G
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