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Asymmetric polyoxometalate electrolytes for advanced redox flow batteries

Lookup NU author(s): Dr Jochen Friedl, Matthäa Holland-Cunz, Faye Cording, Felix Pfanschilling, Dr Corinne Wills, Emeritus Professor William McFarlane, Professor Ulrich Stimming



This is the authors' accepted manuscript of an article that has been published in its final definitive form by Royal Society of Chemistry, 2018.

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© 2018 The Royal Society of Chemistry. Electrochemical storage of energy is a necessary asset for the integration of intermittent renewable energy sources such as wind and solar power into a complete energy scenario. Redox flow batteries (RFBs) are the only type of battery in which the energy content and the power output can be scaled independently, offering flexibility for applications such as load levelling. However, the prevailing technology, the all Vanadium system, comprises low energy and low power densities. In this study we investigate two polyoxometalates (POMs), [SiW12O40]4- and [PV14O42]9-, as nano-sized electron shuttles. We show that these POMs exhibit fast redox kinetics (electron transfer constant k0 ≈ 10-2 cm s-1 for [SiW12O40]4-), thereby enabling high power densities; in addition, they feature multi-electron transfer, realizing a high capacity per molecule; they do not cross cation exchange membranes, eliminating self-discharge through the separator; and they are chemically and electrochemically stable as shown by in situ NMR. In flow battery studies the theoretical capacity (10.7 A h L-1) could be achieved under operating conditions. The cell was cycled for 14 days with current densities in the range of 30 to 60 mA cm-2 (155 cycles). The Coulombic efficiency was 94% during cycling. Very small losses occurred due to residual oxygen in the system. The voltage efficiency (∼65% at 30 mA cm-2) was mainly affected by ohmic rather than kinetic losses. Pathways for further improvement are discussed.

Publication metadata

Author(s): Friedl J, Holland-Cunz MV, Cording F, Pfanschilling FL, Wills C, McFarlane W, Schricker B, Fleck R, Wolfschmidt H, Stimming U

Publication type: Article

Publication status: Published

Journal: Energy and Environmental Science

Year: 2018

Volume: 11

Issue: 10

Pages: 3010-3018

Print publication date: 01/10/2018

Online publication date: 28/07/2018

Acceptance date: 24/07/2018

Date deposited: 02/07/2019

ISSN (print): 1754-5692

ISSN (electronic): 1754-5706

Publisher: Royal Society of Chemistry


DOI: 10.1039/c8ee00422f


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