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Lookup NU author(s): Dr Peter Leary,
Professor Neil GrayORCiD,
This work is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0).
Understanding anthropogenic radionuclide biogeochemistry and mobility in natural systems is key to improving the management of radioactively contaminated environments and radioactive wastes. Here, we describe the contemporary depth distribution and phase partitioning of 137Cs, Pu, and 241Am in two sediment cores taken from the Irish Sea (Site 1: the Irish Sea Mudpatch; Site 2: the Esk Estuary). Both sites are located ~10 km from the Sellafield Ltd. nuclear site. Sellafield Ltd. have disposed of low-level aqueous radioactive wastes into the Irish Sea for >50 y. We compare the depth distribution of the radionuclides at each site to trends in sediment and porewater redox chemistry, using trace element abundance, microbial ecology, and sequential extractions, to better understand the relative importance of sediment biogeochemistry vs. physical controls on radionuclide distribution/post-depositional mobility in the sediments. We highlight that the distribution of 137Cs, Pu, and 241Am at both sites is largely controlled by physical mixing of the sediments, physical transport processes, and sediment accumulation. Interestingly, at the Esk Estuary, microbially-mediated redox processes (considered for Pu) do not appear to offer significant controls on Pu distribution, even over decadal timescales. We also highlight that the Irish Sea Mudpatch likely still acts as a source of historical pollution to other areas in the Irish Sea, despite ever decreasing levels of waste output from the Sellafield Ltd. site.
Author(s): Ray D, Leary P, Livens F, Gray N, Morris K, Law KA, Fuller AJ, Abrahamsen-Mills L, Howe J, Tierney K, Muir G, Law GTW
Publication type: Article
Publication status: Published
Journal: Science of The Total Environment
Print publication date: 15/11/2020
Online publication date: 06/07/2020
Acceptance date: 03/07/2020
Date deposited: 24/07/2020
ISSN (print): 0048-9697
ISSN (electronic): 1879-1026
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