Toggle Main Menu Toggle Search

Open Access padlockePrints

30008. Actinide Metal Carbene Complexes: Synthesis, Structure and Reactivity

Lookup NU author(s): Dr Erli Lu

Downloads

Full text for this publication is not currently held within this repository. Alternative links are provided below where available.


Abstract

This chapter covers the synthesis, structures and reactivity of actinide metal carbene complexes, which feature formal An=C double bonds, since the first examples of such complexes were reported in 1981. In all examples under ‘‘conventional’’ organometallic synthetic conditions, the carbene ligands are mono- or di-anionic, and the An=C bond is stabilized by at least one P(V), P(III) or As(V) substituent. However, in inert-gas matrices or in endohedral fullerenes, unstabilized An=CR2 (R: H, alkyl), and An=C=An, have been reported.


Publication metadata

Author(s): Lu E

Editor(s): Stephen T. Liddle; David Mills

Publication type: Book Chapter

Publication status: In Press

Book Title: Comprehensive Organometallic Chemistry IV

Year: 2021

Acceptance date: 05/01/2021

Publisher: Elsevier


Share