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Lookup NU author(s): Dr Simon DohertyORCiD,
Dr Julian Knight,
This is the authors' accepted manuscript of an article that has been published in its final definitive form by Springer, 2022.
For re-use rights please refer to the publisher's terms and conditions.
The iridium-catalyzed C-H borylation of 3-substituted arylphosphonates with B2pin2 affords the corresponding meta-phosphonate substituted arylboronic esters exclusively which have been used as nucleophilic reagents in a subsequent palladium-catalyzed Suzuki-Miyaura cross-coupling to generate a range of biarylmonophosphonates. Gratifyingly, the Suzuki-Miyaura cross-coupling can be conducted without purifying the boronic ester which greatly simplifies the synthetic procedure.
Author(s): Doherty S, Knight JG, Tran TST, Perry DO
Publication type: Article
Publication status: Published
Journal: Catalysis Letters
Online publication date: 07/05/2021
Acceptance date: 25/04/2021
Date deposited: 27/04/2021
ISSN (print): 1011-372X
ISSN (electronic): 1572-879X
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