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Lookup NU author(s): Dr Paul Waddell,
Dr John ErringtonORCiD
This is the authors' accepted manuscript of an article that has been published in its final definitive form by John Wiley and Sons Inc, 2021.
For re-use rights please refer to the publisher's terms and conditions.
© 2021 Wiley-VCH GmbHSingle-crystal X-ray structure analysis revealed the precise structure of a Ce-encapsulated Preyssler-type phosphotungstate which was first synthesized by Pope et al. Antonio et al. reported that encapsulated Ce has a 3+ oxidation state and is redox-inactive, which is unlike other Ce-containing phosphotungstates. Therefore, precise structural analysis about Ce position is needed. The encapsulated Ce was located in one of the side cavities, and was coordinated to one H2O molecule. The position of Ce was similar to that of Y3+ and Eu3+ in similar compounds. This result, together with the bond valence sum calculation, provides additional evidence that the oxidation state of the redox-inactive Ce in the Preyssler-type compound is 3+.
Author(s): Shitamatsu K, Kojima T, Waddell PG, Sugiarto, Ooyama HE, Errington RJ, Sadakane M
Publication type: Article
Publication status: Published
Journal: Zeitschrift fur Anorganische und Allgemeine Chemie
Print publication date: 11/06/2021
Online publication date: 20/04/2021
Acceptance date: 06/04/2021
Date deposited: 13/05/2021
ISSN (print): 0044-2313
ISSN (electronic): 1521-3749
Publisher: John Wiley and Sons Inc
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