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Benzothiazolium Salts as Reagents for the Deoxygenative Perfluoroalkylthiolation of Alcohols

Lookup NU author(s): Dr Matt HopkinsonORCiD

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This work is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0).

Abstract

A series of 2-(perfluoroalkylthio)benzothiazolium (BT-SRF) salts have been synthesized that serve as convenient sources of hitherto underexplored perfluoroalkylthiolate anions. An investigation of their reactivity in a deoxygenative nucleophilic substitution reaction led to the development of an unprecedented process that provides pentafluoroethyl and heptafluoropropyl thioethers directly from readily available alcohols.

Publication metadata

Author(s): Ariamajd A, Gerwien NJ, Schwabe B, Dix S, Hopkinson MN

Publication type: Article

Publication status: Published

Journal: Beilstein Journal of Organic Chemistry

Year: 2021

Volume: 17

Pages: 83-88

Online publication date: 08/01/2021

Acceptance date: 11/12/2020

Date deposited: 16/11/2021

ISSN (electronic): 1860-5397

Publisher: Beilstein-Institut

URL: https://www.beilstein-journals.org/bjoc/articles/17/8

DOI: 10.3762/bjoc.17.8

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