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Oxidative Addition to Gold(I) by Photoredox Catalysis: Straightforward Access to Diverse (C,N)-Cyclometalated Gold(III) Complexes

Lookup NU author(s): Dr Matt HopkinsonORCiD

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Abstract

Access diverse gold(III) complexes: The oxidative addition of aryldiazonium salts to gold(I) complexes under visible light photoredox conditions provides experimental evidence for the involvement of such a process in dual gold/photoredox-catalyzed reactions. Moreover, this method delivers well-defined and stable (C,N)-cyclometalated gold(III) species. As demonstrated here, the mild reaction conditions and the ability to widely vary the supporting ligand make this method a powerful synthetic tool to access diverse gold(III) complexes for systematic studies into the properties and reactivity of this important class of organometallic species.

Publication metadata

Author(s): Tlahuext-Aca A, Hopkinson MN, Daniliuc CG, Glorius F

Publication type: Article

Publication status: Published

Journal: Chemistry - A European Journal

Year: 2016

Volume: 22

Issue: 33

Pages: 11587-11592

Print publication date: 01/08/2016

Online publication date: 14/07/2016

Acceptance date: 24/06/2016

ISSN (print): 0947-6539

ISSN (electronic): 1521-3765

Publisher: Wiley

URL: https://doi.org/10.1002/chem.201602649

DOI: 10.1002/chem.201602649

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