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Combining gold and photoredox catalysis: Visible light-mediated oxy-and aminoarylation of alkenes

Lookup NU author(s): Dr Matt HopkinsonORCiD

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Abstract

A room-temperature intramolecular oxy-and aminoarylation of alkenes with aryldiazonium salts has been developed using a novel gold and photoredox dual-catalytic system. The compatibility of these two catalytic modes has been established for the first time and demonstrates the potential of this system as a method to expand the scope of nucleophilic addition reactions to carbon-carbon multiple bonds. © 2013 American Chemical Society.

Publication metadata

Author(s): Sahoo B, Hopkinson MN, Glorius F

Publication type: Article

Publication status: Published

Journal: Journal of the American Chemical Society

Year: 2013

Volume: 135

Issue: 15

Pages: 5505-5508

Print publication date: 17/04/2013

Online publication date: 03/04/2013

ISSN (print): 0002-7863

ISSN (electronic): 1520-5126

Publisher: American Chemical Society

URL: https://doi.org/10.1021/ja400311h

DOI: 10.1021/ja400311h

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