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Palladium-catalyzed allylic fluorination

Lookup NU author(s): Dr Matt HopkinsonORCiD

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Abstract

Mild and rapid: The title reaction is presented and its applicability to 18F radiolabeling is demonstrated (see scheme; TBAF=tetra-n- butylammonium fluoride, THF=tetrahydrofuran, dba=dibenzylideneacetone). The use of p-nitrobenzoate as the leaving group is significant to the success of this catalytic organometallic fluorination process. A range of allylic fluorides were synthesized by this method. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Publication metadata

Author(s): Hollingworth C, Hazari A, Hopkinson MN, Tredwell M, Benedetto E, Huiban M, Gee AD, Brown JM, Gouverneur V

Publication type: Article

Publication status: Published

Journal: Angewandte Chemie - International Edition

Year: 2011

Volume: 50

Issue: 11

Pages: 2613-2617

Print publication date: 07/03/2011

Online publication date: 08/02/2011

ISSN (print): 1433-7851

ISSN (electronic): 1521-3773

Publisher: Wiley-VCH Verlag

URL: https://doi.org/10.1002/anie.201007307

DOI: 10.1002/anie.201007307

PubMed id: 21370349

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