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Gold-catalyzed intramolecular oxidative cross-coupling of nonactivated arenes

Lookup NU author(s): Dr Matt HopkinsonORCiD

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Abstract

(Chemical Equatation Reprentation An (Au)some coupling! Gold-catalyzed cascade C-O cyclizations of benzyl-substituted allenoate esters followed by intramolecular oxidative C-C cross-coupling involving aryl C-H functionalization were performed with Selectfluor as the oxidant (see scheme). This operationally simple and mild procedure benefits from complete axis-to-center chirality transfer and allows for the preparation of surprisingly uncommon tricyclic motifs. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

Publication metadata

Author(s): Hopkinson MN, Tessier A, Salisbury A, Giuffredi GT, Combettes LE, Gee AD, Gouverneur V

Publication type: Article

Publication status: Published

Journal: Chemistry - A European Journal

Year: 2010

Volume: 16

Issue: 16

Pages: 4739-4743

Print publication date: 16/04/2010

Online publication date: 25/03/2010

ISSN (print): 0947-6539

ISSN (electronic): 1521-3765

Publisher: Wiley-VCH Verlag GmbH & Co. KGaA

URL: https://doi.org/10.1002/chem.201000322

DOI: 10.1002/chem.201000322

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