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Dual Photoredox and Gold Catalysis: Intermolecular Multicomponent Oxyarylation of Alkenes

Lookup NU author(s): Dr Matt HopkinsonORCiD

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Abstract

© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Intermolecular three-component oxyarylation reactions of simple alkenes have been developed using a dual gold and photoredox catalytic system. Inexpensive organic dyes could be employed as the photocatalyst using aryldiazonium salts, while the combination of gold and iridium catalysts allowed for diaryliodonium compounds to be employed as the source of the arene coupling partner. In both cases, α-arylated ether products were generated under remarkably mild conditions using readily accessible visible light sources.

Publication metadata

Author(s): Hopkinson MN, Sahoo B, Glorius F

Publication type: Article

Publication status: Published

Journal: Advanced Synthesis and Catalysis

Year: 2014

Volume: 356

Issue: 13

Pages: 2794-2800

Print publication date: 15/09/2014

Online publication date: 11/09/2014

Acceptance date: 15/06/2014

ISSN (print): 1615-4150

ISSN (electronic): 1615-4169

Publisher: Wiley-VCH Verlag

URL: https://doi.org/10.1002/adsc.201400580

DOI: 10.1002/adsc.201400580

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