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Lookup NU author(s): Dr Macesic Macesic,
Dr Katarina Novakovic
This is the authors' accepted manuscript of an article that has been published in its final definitive form by Springer, 2022.
For re-use rights please refer to the publisher's terms and conditions.
The study presents a mathematical model of Bruk Temkin-Gorodsky Novakovic (BT-GN) reaction system employing palladium-catalyzed oscillatory carbonylation reaction of mono alkyne-terminated poly(ethylene glycol) methyl ether. The proposed model advances simulation capabilities of this particular chemical oscillator but also BT-GN reactions in general. The model was verified using experimental data where good agreement is achieved and existence of complex pH oscillations like burst oscillations was matched. Furthermore, the model was used to predict reaction conditions capable of producing further complexities and initial conditions that would lead to desired period of pH oscillations. Having such a powerful tool, enhances our capabilities to study and further develop BT-GN oscillators with a reduced experimental effort.
Author(s): Cupic Z, Macesic S, Anic S, Kolar-Anic Lj, Ivanovic-Sasic A, Novakovic K
Publication type: Article
Publication status: Published
Journal: Reaction Kinetics, Mechanisms and Catalysis
Issue: ePub ahead of Print
Online publication date: 08/01/2022
Acceptance date: 30/12/2021
Date deposited: 19/01/2022
ISSN (print): 1878-5190
ISSN (electronic): 1878-5204
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