Browse by author
Lookup NU author(s): Dr Julien EngORCiD, Professor Thomas Penfold
This work is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0).
Here two D–A3 regioisomers, comprising three dibenzothiophene-S,S-dioxide acceptor units attached to a central triazatruxene core, are studied. Both molecules show thermally activated delayed fluorescence (TADF), however, the efficiency of the TADF mechanism is strongly affected by the D–A substitution position. The meta- substituted emitter (1b) shows a slightly higher-lying singlet charge transfer state and a lower-lying triplet state than that observed in the para- substituted emitter (1a), resulting in a larger singlet–triplet splitting (ΔEST) of 0.28 eV compared to only 0.01 eV found in 1a. As expected, this ΔEST difference strongly impacts the reverse intersystem crossing (rISC) rates and the para- isomer 1a exhibits a much faster delayed fluorescence emission. Calculations show that the triplet energy difference between the two isomers is due to steric hindrance variances along the donor–acceptor rotation axis in these molecules: as 1b is less restricted, rotation of its acceptor unit leads to a lower T1 energy, further away from the region of high density of states (the region where larger vibronic coupling is found, favouring rISC). Therefore, our results show how the substitution pattern has a marked effect on triplet state energies and character, verifying the key structural designs for highly efficient TADF materials.
Author(s): dos Santos PL, de Sa Pereira D, Eng J, Ward JS, Bryce MR, Penfold TJ, Monkman AP
Publication type: Article
Publication status: Published
Journal: ChemPhotoChem
Year: 2022
Volume: 7
Issue: 2
Print publication date: 01/02/2023
Online publication date: 20/10/2022
Acceptance date: 14/10/2022
Date deposited: 21/10/2022
ISSN (electronic): 2367-0932
Publisher: Wiley-VCH Verlag GmbH & Co. KGaA
URL: https://doi.org/10.1002/cptc.202200248
DOI: 10.1002/cptc.202200248
Altmetrics provided by Altmetric