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Enhanced Adsorption of Methylene Blue Using Phosphoric Acid-Activated Hydrothermal Carbon Microspheres Synthesized from a Variety of Palm-Based Biowastes

Lookup NU author(s): Professor Chun Yang Yin

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This work is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0).


Abstract

© 2023 by the authors.In the present study, the ability for novel carbon microspheres (CMs) derived from date palm (Phoenix dactylifera) biomass using a hydrothermal carbonization (HTC) process and activated using phosphoric acid to remove methylene blue dye was investigated. Three types of palm-based wastes (seeds, leaflet, and inedible crystallized date palm molasses) were used and converted to CMs via the HTC process. The prepared samples were then activated using phosphoric acid via the incipient wetness impregnation method. The CMs samples before and after activation were analyzed using scanning electron microscopy (SEM), elemental analysis and scanning (CHNS), and the Fourier transform infrared (FTIR) and Brunauer–Emmet–Teller (BET) methods. The samples exhibited high BET surface areas after activation (1584 m2/g). The methylene blue adsorption results showed good fitting to the Langmuir, Fruendlich, and Temkin isotherm models for all activated samples. The maximum adsorption capacity achieved was 409.84 mg/g for activated CM obtained from the palm date molasses, indicating its high potential for application as a dye-based adsorption material.


Publication metadata

Author(s): Alhawtali S, El-Harbawi M, Al-Awadi AS, El Blidi L, Alrashed MM, Yin C-Y

Publication type: Article

Publication status: Published

Journal: Coatings

Year: 2023

Volume: 13

Issue: 7

Print publication date: 01/07/2023

Online publication date: 22/07/2023

Acceptance date: 20/07/2023

Date deposited: 12/09/2023

ISSN (electronic): 2079-6412

Publisher: Multidisciplinary Digital Publishing Institute (MDPI)

URL: https://doi.org/10.3390/coatings13071287

DOI: 10.3390/coatings13071287

Data Access Statement: Not applicable.


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Funding

Funder referenceFunder name
Deputyship for Research and Innovation, “Ministry of Education”, Saudi Arabia
IFKSUDR_F158

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