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Facile Mechanochemical Reduction and Lithium-Ion Doping of Transition-Metal Oxides[]**

Lookup NU author(s): Dr Nathan Davison, Dr Isabel Arce-Garcia, Dr James DawsonORCiD, Dr Erli Lu

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This work is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0).


Abstract

© 2023 The Authors. European Journal of Inorganic Chemistry published by Wiley-VCH GmbH. Transition-metal oxides (MOx) play essential roles in chemistry, catalysis, materials science and metallurgy. The MOx reduction and doping are two ubiquitous reactions in academic research and industrial manufacturing, but they are notoriously energy-demanding and require harsh conditions (high temperatures, long durations). In this work, facilitated by mechanochemical ball milling, we report a new route to conduct MOx reduction and doping at room temperature within 20 minutes enabled by mechanochemical ball milling and lithium metal.


Publication metadata

Author(s): Davison N, Khatun T, Arce-Garcia I, Gould JA, Dawson JA, Lu E

Publication type: Article

Publication status: Published

Journal: European Journal of Inorganic Chemistry

Year: 2023

Volume: 26

Issue: 35

Print publication date: 12/12/2023

Online publication date: 18/10/2023

Acceptance date: 06/10/2023

Date deposited: 03/11/2023

ISSN (print): 1434-1948

ISSN (electronic): 1099-0682

Publisher: John Wiley and Sons Inc.

URL: https://doi.org/10.1002/ejic.202300344

DOI: 10.1002/ejic.202300344

Data Access Statement: The data that support the findings of this study are available in the supplementary material of this article.


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Funding

Funder referenceFunder name
EP/L000202/1
EP/T022213
EP/V013130/1
EPSRC North East Centre of Energy Materials (NECEM)
E20-5153
E22-3348740748
EP/L000202
EP/R029431
EPSRC
Newcastle University Academic Track (NUAcT)
Newcastle University
Royal Society of Chemistry
UK's HEC Materials Chemistry Consortium

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