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Lithium, sodium and potassium enolate aggregates and monomers: syntheses and structures

Lookup NU author(s): Dr Nathan Davison, Dr Jack Hemingway, Dr Paul Waddell, Dr Erli Lu

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Abstract

© 2024 The Royal Society of Chemistry. In this Article, we report the syntheses and comparative structural studies of lithium, sodium, and potassium anthracen-9-yl enolates, as their aggregates (Li, Na: hexamer; K: tetramer) and ligand-stabilized monomers (for Li and Na). The monomers add new members to the rare collection of group-1 metal monomeric enolates. Moreover, the series covers different group-1 metal cations (Li+, Na+ and K+) and aggregate sizes, allowing comparative structural studies to elucidate how the metal identity and aggregate size influence the enolate structure.

Publication metadata

Author(s): Davison N, Hemingway JM, Waddell PG, Lu E

Publication type: Article

Publication status: Published

Journal: Dalton Transactions

Year: 2024

Volume: 53

Pages: 4719-4728

Online publication date: 12/02/2024

Acceptance date: 09/02/2024

Date deposited: 05/03/2024

ISSN (print): 1477-9226

ISSN (electronic): 1477-9234

Publisher: Royal Society of Chemistry

URL: https://doi.org/10.1039/d4dt00211c

DOI: 10.1039/d4dt00211c

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