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Conformational Control of Donor–Acceptor Molecules Using Non-covalent Interactions

Lookup NU author(s): Shawana Ahmad, Dr Julien EngORCiD, Professor Thomas Penfold

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This work is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0).


Abstract

Controlling the architecture of organic molecules is an important aspect in tuning the functional properties of components in organic electronics. For purely organic thermally activated delayed fluorescence (TADF) molecules, design is focused upon orthogonality orientated donor and acceptor units. In these systems, the rotational dynamics around the donor and acceptor bond has been shown to be critical for activating TADF; however, too much conformational freedom can increase the non-radiative rate, leading to a large energy dispersion of the emitting states and conformers, which do not exhibit TADF. To date, control of the motion around the D–A bond has focused upon steric hindrance. In this work, we computationally investigate eight proposed donor–acceptor molecules, exhibiting a B–N bond between the donor and acceptor. We compare the effect of steric hindrance and noncovalent interactions, achieved using oxygen (sulfur) boron heteroatom interactions, in exerting fine conformational control of the excited state dynamics. This work reveals the potential for judiciously chosen noncovalent interactions to strongly influence the functional properties of TADF emitters, including the accessible conformers and the energy dispersion associated with the charge transfer states.


Publication metadata

Author(s): Ahmad S, Eng J, Penfold TJ

Publication type: Article

Publication status: Published

Journal: Journal of Physical Chemistry A

Year: 2024

Pages: epub ahead of print

Online publication date: 17/09/2024

Acceptance date: 05/09/2024

Date deposited: 17/09/2024

ISSN (print): 1089-5639

ISSN (electronic): 1520-5215

Publisher: ACS

URL: https://doi.org/10.1021/acs.jpca.4c03711

DOI: 10.1021/acs.jpca.4c03711

Data Access Statement: The data supporting this publication are openly available under an Open Data Commons Open Database License. Additional metadata are available at 10.25405/data.ncl.25962481


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Funding

Funder referenceFunder name
EP/X026973/1
EP/T022442/1
EPSRC

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