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Lookup NU author(s): Dr Liam McGarry, Dr Osama El-ZubirORCiD, Professor Andrew HoultonORCiD, Dr Ben HorrocksORCiD
This work is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0).
© 2025 The Author(s). Chemistry - A European Journal published by Wiley-VCH GmbH.Heterometallic coordination polymers of Au(I) and Ag(I) with 6-thioguanosine, poly((Formula presented.)), have been prepared and were observed to form hydrogels. We find that the composition of the heterometallic polymer is proportional to the mole fractions of the metals in the preparation solution. Optical absorption spectra show single peaks for (Formula presented.) nm which can be interpolated in a linear manner between x (Formula presented.) and x (Formula presented.) consistent with the formation of a heterometallic polymer rather than a mixture of homopolymers. However photoluminescence and circular dichroism spectra are sensitive to the supramolecular structure of the polymers and show more complex behaviour. Atomic force microscopy indicated that the molecular chains of the Au homopolymer entwine to form strands that are predominantly right-hand helices. The Ag homopolymer has previously been shown to form left-hand helices. Intermediate compositions have more complex structures because of the competition between the left and right-handed preferences of the homopolymers. Finally, we have shown that the metal-ligand bonds are labile on a timescale of about 5 h at ambient temperature (about 293 K). Mixtures of homopolymers transform to the corresponding heterometallic coordination polymer by metal exchange as judged by optical absorption, photoluminescence and circular dichroism spectra.
Author(s): Tangsombun C, McGarry LF, El-Zubir O, Houlton A, Horrocks BR
Publication type: Article
Publication status: Published
Journal: Chemistry - A European Journal
Year: 2025
Pages: epub ahead of print
Online publication date: 03/02/2025
Acceptance date: 02/04/2018
Date deposited: 10/03/2025
ISSN (print): 0947-6539
ISSN (electronic): 1521-3765
Publisher: John Wiley and Sons Inc
URL: https://doi.org/10.1002/chem.202404318
DOI: 10.1002/chem.202404318
Data Access Statement: The data that support the findings of this study are openly available in https://data.ncl.ac.uk at https://doi.org/10.25405/ data.ncl.27652962, reference number 27652962
